Cooking Oil Data

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Cooking Oil Data

Table 1: FATTY ACID CONTENT OF COOKING OILS (percentages)

TYPE OF OIL POLYUNSATURATED MONOUNSATURATED SATURATED
Omega-3 Omega-6
ALA EPA DHA LA GLA 16:1 18:1 20:1 22:1 10:0 12:0 14:0 16:0 18:0 20:0 22:0 24:0
Almond       17   1 69           6 2      
Avocado 1     13   3 68           11 1      
Canola 9     20   tr 56 2 1       4 2 1 tr tr
Coconut       2     6     6 45 17 8 3      
Corn 1     53   tr 27 tr       tr 11 2 tr    
Cottonseed tr     52   1 17         1 23 2      
Fish-salmon ** 3 12 5 10     3         4 10 1      
Flaxseed ** 53     13     20           5 4      
Grapeseed tr     70   tr 16         tr 7 3      
Olive 1     9   1 72 tr         11 2 tr tr  
Palm tr     9   tr 37 tr     tr 1 44 4      
Peanut       32   tr 45 1       tr 10 2 1 3 1
Primrose **       63 13   12           9 1      
Rice Bran 2     33   tr 39         1 17 2      
Safflower-P       75     14           4 2      
Safflower-M       14     75           4 2      
Sesame tr     41   tr 39 tr         9 5      
Soybean 7     51   tr 23 tr       tr 10 4      
Sunflower-P       66     20           6 4      
Sunflower-M tr     4     83 1         4 4   1  
Walnut 10     53   tr 22 tr         7 2      

ABBREVIATIONS:

16:0, 16:1, etc.   = A fatty acid chain with the # of carbon atoms equal to 16, and the number of doubly-bonded carbon atoms equal to 0, 1, etc.

ALA =   alpha-linolenic acid (18:3)
EPA =   eicosapentaenoic acid (20:5)
DHA =   docosahexaenoic acid (22:6)
LA   =   linoleic acid (18:2)
GLA =   gamma-linolenic acid (18:3)

Safflower-P and safflower-M are the high-polyunsaturated and high-monounsaturated varieties of this oil (as also for sunflower oil), respectively.

tr   =   trace amount (less than 0.5%)

**   =   not a cooking oil (included for the purpose of comparison)

DATA SOURCES:

The above data are from the USDA food composition tables except that the fish oil and primrose oil data are from a medical journal.   A brief introduction to fatty acids can be found in the online encyclopedia called Wikipedia.  A much more detailed discussion can be found at the Web site of the Institute of Shortening and Edible Oils (ISEO).



NOTES REGARDING TABLE 1:

1) Olive oil has a large percentage of monosaturated fatty acids and is therefore resistant to rancidity.  Minor ingredients such a Vitamin-E and phenols also contribute to this resistance.

2) Omega-3 fatty acids are essential for good health but are deficient in most people's diets.   These substances are best obtained from fish or from fish oil supplements containing standardized amounts of EPA and DHA.

3) Omega-6 fatty acids are a major component of most plant oils.  These substances are essential nutrients but are so common in a normal diet that most people have too large of a ratio of omega-6 fatty acids to omega-3 fatty acids.  An exception to this situation occurs for people who are deficient in an enzyme which converts LA to the essential nutrient GLA.  In such cases, a GLA supplement such as primrose oil is needed.

4) Alpha-linoleic acid (ALA) can be converted by the digestive system to the more usable EPA and DHA but the efficiency of this conversion is controversial.

5) Saturated fats increase LDL (or "bad") cholesterol in the blood stream and significantly increase the incidence of heart disease according to several population studies.  However, palm and coconut oils, both of which are high in saturated fats, do not appear to produce health problems in countries that have used them for centuries.  Thus, there is no strict rule that saturated fats are bad, particulary if they are combined with other dietary components that counteract their effects.

6) Trans fatty acids are not present in cooking oils.  Rather, they are the result of the hydrogenation of a cooking oil to form a rigid margarine.  Trans fats appear to be correlated with heart disease.

7) Cholesterol is never present in more than trace amounts in cooking oils.  However, cooking oils can influence the amounts of LDL and HDL cholesterol in the blood.

8) Animal oils:  Extensive fatty acid tables for animal oils (e.g. chicken, eggs) can be found at the IUPAC Web site.




Table 2: MINOR COMPONENTS OF COOKING OILS   (PPM)

TYPE OF OIL PHYTOSTEROLS TOCOPHEROLS TOCOTRIENOLS POLYPHENOLS VITAMIN K SQUALENE
Almond 2660 392 0 0 0.07  
Avocado 0 0   6 0  
Canola 0 484   4 1.22  
Coconut 860 3 22   0.01  
Corn 9680 143     0.02  
Cottonseed 3240 353 30   0.25  
Flaxseed 0 175     0  
Grapeseed 1800 288   2 0  
Olive 2210 153 0 48 0.60 5000
Palm 0 159 720   0.08  
Peanut 2070 334   0 0.01  
Rice Bran 11900 323 1000   0.25 3500
Safflower-P 4440 341 8   0.07  
Safflower-M 4440 341 0   0.07  
Sesame 8650 14   6 0.14  
Soybean 2500 92 86 4 1.98  
Sunflower-P 1000 411 0 0 0.05 60
Sunflower-M 1000 411   0 0.05 60
Walnut 1760 4   0 0.15  

DATA SOURCES:

Phytosterols:  These are polycyclic alcohols which occur in plants ("phyto-" is a prefix meaning "plant").  Evidence suggests that phytosterols may play a significant role in regulating blood cholesterol.  Their Table 2 data come from the USDA food composition tables.

Tocopherols:  These are isomeric fat-soluble alcohols which include Vitamin E (alpha-tocopherol).  Their antioxidant property helps to keep cooking oils from becoming rancid.  Their Table 2 data come from the USDA food composition tables.

Tocotrienols:  These compounds are closely related to tocopherols and have Vitamin E activity.  Their Table 2 data (except for rice bran oil) come from the Seed Oil Fatty Acids (SOFA) database.  The SOFA database can be most easily searched by inserting a single word (e.g. corn, safflower, etc.) into the Freetext block of the search form and leaving the rest of the search form blank.

Polyphenols:  These are loosely defined as aromatic alcohols with 1 or more hydroxy group (strictly speaking, phenols with 1 hydroxy group should not be called polyphenols).  They, like tocopherols and tocotrienols, function as antioxidants and help keep cooking oils from becoming rancid.  Their Table 2 data come from an online research journal article (Asia Pacific J Clin Nutr (1996) 5: 105-107).

Vitamin K:  A fat-soluble cyclic ketone that promotes blood clotting; also called phylloquinone.  The Table 2 data for Vitamin K come from the USDA food composition tables.

Squalene:  A metabolic precursor of cholesterol which has exhibited anti-cancer properties in animal studies.  The Table 2 data for squalene (except for rice bran oil) come from an abstract of an article in the European Journal of Cancer Prevention 12(1):67-75, Feb 2003.  Seed oils contain only minimal amounts of squalene, and there is no convenient data source to which to link to such data.

NOTES REGARDING TABLE 2:

1) All of the Table 2 data presumably refer to refined oils although none of the data sources explicitly say so.  Unrefined oils are much richer in minor components than refined oils.

2) Commercial cooking oils have standards for peroxide content (i.e. degree of rancidity).  However, these standards are often not strict enough for highly sensitive individuals such as myself.

3) The ingredients listed in Table 2 are generally regarded as having a positive effect on health.  The refining process attempts to remove whatever ingredients are known to have negative effects.



Table 3: COOKING OIL SYMPTOMS VS. MANUFACTURING METHOD: a one-man study

TYPE OF OIL LOW TEMP MANUFACTURING HIGH TEMP MANUFACTURING
  DOSAGE SYMPTOMS DOSAGE SYMPTOMS
Almond high none    
Avocado med sore neck    
Canola high none low headache
Corn high none low headache
Grapeseed high none    
Olive high none    
Peanut high none low headache
Safflower: High poly low sore neck    
Safflower: High mono high mildly sore neck    
Sesame high none    
Sunflower: High poly high none    
Sunflower: High mono     med slight queasiness


KEY:
Low dosage      = a few drops
medium dosage = 1 teaspoon
high dosage      = 1 ounce in 1 day

NOTES REGARDING TABLE 3:
1) The most plausible explanation for the symptoms shown in Table 3 is that I am sensitive to peroxides which arise via the oxidation of oils during manufacturing.  The strongest evidence for this is that corn oil, peanut oil and canola oil do not cause me symptoms when they are produced via expeller pressing, but cause headaches when they are manufactured via the conventional high-temperature process.  Few people experience noticeable symptoms from ingesting cheap cooking oils but that does not mean that the oils are high quality.  If they were high quality, there would be no reason for health-food stores to offer the expeller-pressed oils as an alternative.

2) All of the oils in the above table were refined except for sesame oil.

3) The oils obtained by low-temperature manufacturing were expeller pressed, except for grapeseed oil, which must be solvent extracted.